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A fully solid-state cold thermal energy storage device for car seats using shape-memory alloys

《能源前沿(英文)》 2023年 第17卷 第4期   页码 504-515 doi: 10.1007/s11708-022-0855-3

摘要: Thermal energy storage has been a pivotal technology to fill the gap between energy demands and energy supplies. As a solid-solid phase change material, shape-memory alloys (SMAs) have the inherent advantages of leakage free, no encapsulation, negligible volume variation, as well as superior energy storage properties such as high thermal conductivity (compared with ice and paraffin) and volumetric energy density, making them excellent thermal energy storage materials. Considering these characteristics, the design of the shape-memory alloy based the cold thermal energy storage system for precooling car seat application is introduced in this paper based on the proposed shape-memory alloy-based cold thermal energy storage cycle. The simulation results show that the minimum temperature of the metal boss under the seat reaches 26.2 °C at 9.85 s, which is reduced by 9.8 °C, and the energy storage efficiency of the device is 66%. The influence of initial temperature, elastocaloric materials, and the shape-memory alloy geometry scheme on the performance of car seat cold thermal energy storage devices is also discussed. Since SMAs are both solid-state refrigerants and thermal energy storage materials, hopefully the proposed concept can promote the development of more promising shape-memory alloy-based cold and hot thermal energy storage devices.

关键词: shape-memory alloy (SMA)     elastocaloric effect (eCE)     cooled seat     cold thermal energy storage    

Fabrication of form stable NaCl-Al2O3 composite for thermal energy storage by cold sintering process

Bilyaminu Suleiman, Qinghua Yu, Yulong Ding, Yongliang Li

《化学科学与工程前沿(英文)》 2019年 第13卷 第4期   页码 727-735 doi: 10.1007/s11705-019-1823-2

摘要: A form stable NaCl-Al O (50-50 wt-%) composite material for high temperature thermal energy storage was fabricated by cold sintering process, a process recently applied to the densification of ceramics at low temperature ˂ 300°C under uniaxial pressure in the presence of small amount of transient liquid. The fabricated composite achieved as high as 98.65% of the theoretical density. The NaCl-Al O composite also retained the chloride salt without leakage after 30 heating-cooling cycles between 750°C–850°C together with a holding period of 24 h at 850°C. X-ray diffraction measurements indicated congruent solubility of the alumina in chloride salt, excellent compatibility of NaCl with Al O , and chemical stability at high temperature. Structural analysis by scanning electron microscope also showed limited grain growth, high density, uniform NaCl distribution and clear faceted composite structure without inter-diffusion. The latent heat storage density of 252.5 J/g was obtained from simultaneous thermal analysis. Fracture strength test showed high sintered strength around 5 GPa after 50 min. The composite was found to have fair mass losses due to volatilization. Overall, cold sintering process has the potential to be an efficient, safe and cost-effective strategy for the fabrication of high temperature thermal energy storage materials.

关键词: cold sintering process     composite fabrication     thermal energy storage     phase change materials    

Numerical simulation of underground seasonal cold energy storage for a 10 MW solar thermal power plant

Zulkarnain ABBAS, Yong LI, Ruzhu WANG

《能源前沿(英文)》 2021年 第15卷 第2期   页码 328-344 doi: 10.1007/s11708-020-0676-1

摘要: This paper aims to explore an efficient, cost-effective, and water-saving seasonal cold energy storage technique based on borehole heat exchangers to cool the condenser water in a 10 MW solar thermal power plant. The proposed seasonal cooling mechanism is designed for the areas under typical weather conditions to utilize the low ambient temperature during the winter season and to store cold energy. The main objective of this paper is to utilize the storage unit in the peak summer months to cool the condenser water and to replace the dry cooling system. Using the simulation platform transient system simulation program (TRNSYS), the borehole thermal energy storage (BTES) system model has been developed and the dynamic capacity of the system in the charging and discharging mode of cold energy for one-year operation is studied. The typical meteorological year (TMY) data of Dunhuang, Gansu province, in north-western China, is utilized to determine the lowest ambient temperature and operation time of the system to store cold energy. The proposed seasonal cooling system is capable of enhancing the efficiency of a solar thermal power plant up to 1.54% and 2.74% in comparison with the water-cooled condenser system and air-cooled condenser system respectively. The techno-economic assessment of the proposed technique also supports its integration with the condenser unit in the solar thermal power plant. This technique has also a great potential to save the water in desert areas.

关键词: seasonal cold energy storage     borehole heat exchangers     typical meteorological data     TRNSYS     condenser cooling     techno-economic assessment    

Combined heat and power plant integrated with mobilized thermal energy storage (M-TES) system

Weilong WANG, Yukun HU, Jinyue YAN, Jenny NYSTR?M, Erik DAHLQUIST

《能源前沿(英文)》 2010年 第4卷 第4期   页码 469-474 doi: 10.1007/s11708-010-0123-9

摘要: Energy consumption for space and tap water heating in residential and service sectors accounts for one third of the total energy utilization in Sweden. District heating (DH) is used to supply heat to areas with high energy demand. However, there are still detached houses and sparse areas that are not connected to a DH network. In such areas, electrical heating or oil/pellet boilers are used to meet the heat demand. Extending the existing DH network to those spare areas is not economically feasible because of the small heat demand and the large investment required for the expansion. The mobilized thermal energy storage (M-TES) system is an alternative source of heat for detached buildings or sparse areas using industrial heat. In this paper, the integration of a combined heat and power (CHP) plant and an M-TES system is analyzed. Furthermore, the impacts of four options of the integrated system are discussed, including the power and heat output in the CHP plant. The performance of the M-TES system is likewise discussed.

关键词: Mobilized thermal energy system     district heating     thermal energy storage     combined heat and power     detached houses    

Experimental study and assessment of thermal energy storage mortar with paraffin/recycled brick powder

Luchen HAO; Jianzhuang XIAO; Wanzhi CAO; Jingting SUN

《结构与土木工程前沿(英文)》 2022年 第16卷 第10期   页码 1301-1314 doi: 10.1007/s11709-022-0883-4

摘要: Thermal energy storage recycled powder mortar (TESRM) was developed in this study by incorporating paraffin/recycled brick powder (paraffin/BP) composite phase change materials (PCM). Fourier transform infrared and thermogravimetric analysis results showed that paraffin/BP composite PCM had good chemical and thermal stability. The onset melting temperature and latent heat of the composite PCM were 46.49 °C and 30.1 J·g−1. The fresh mortar properties and hardened properties were also investigated in this study. Paraffin/BP composite PCM with replacement ratio of 0%, 10%, 20%, and 30% by weight of cement were studied. The results showed that the static and dynamic yield stresses of TESRM were 699.4% and 172.9% higher than those of normal mortar, respectively. The addition of paraffin/BP composite PCM had a positive impact on the mechanical properties of mortar at later ages, and could also reduce the dry shrinkage of mortar. The dry shrinkage of TESRM had a maximum reduction about 26.15% at 120 d. The thermal properties of TESRM were better than those of normal mortar. The thermal conductivity of TESRM was 36.3% less than that of normal mortar and the heating test results showed that TESRM had good thermal energy storage performance.

关键词: recycled powder mortar     recycled brick powder     thermal energy storage     paraffin     phase change material    

Encapsulation of polyethylene glycol in cellulose-based porous capsules for latent heat storage and light-to-thermal

《化学科学与工程前沿(英文)》 2023年 第17卷 第8期   页码 1038-1050 doi: 10.1007/s11705-022-2279-3

摘要: Phase change materials are potential candidates for the application of latent heat storage. Herein, we fabricated porous capsules as shape-stable materials from cellulose-based polyelectrolyte complex, which were first prepared using cellulose 6-(N-pyridinium)hexanoyl ester as the cationic polyelectrolyte and carboxymethyl cellulose as the anionic polyelectrolyte to encapsulate polyethylene glycol by the vacuum impregnation method. Furthermore, the multi-walled carbon nanotube or graphene oxide, which were separately composited into the polyelectrolytes complex capsules to enhance thermal conductivity and light-to-thermal conversion efficiency. These capsules owned a typical core–shell structure, with an extremely high polyethylene glycol loading up to 34.33 g∙g‒1. After loading of polyethylene glycol, the resulted cellulose-based composite phase change materials exhibited high thermal energy storage ability with the latent heat up to 142.2 J∙g‒1, which was 98.5% of pure polyethylene glycol. Further results showed that the composite phase change materials demonstrated good form-stable property and thermal stability. Moreover, studies involving light-to-thermal conversion determined that composite phase change materials exhibited outstanding light-to-thermal conversion performance. Considering their exceptional comprehensive features, innovative composite phase change materials generated from cellulose presented a highly interesting choice for thermal management and renewable thermal energy storage.

关键词: cellulose     polyelectrolytes     phase change materials     thermal energy storage     light-to-thermal conversion    

Non-thermal plasma enhances performances of biochar in wastewater treatment and energy storage applications

《化学科学与工程前沿(英文)》 2022年 第16卷 第4期   页码 475-483 doi: 10.1007/s11705-021-2070-x

摘要: Surface functionalization or modification to introduce more oxygen-containing functional groups to biochar is an effective strategy for tuning the physicochemical properties and promoting follow-up applications. In this study, non-thermal plasma was applied for biochar surface carving before being used in contaminant removal and energy storage applications. The results showed that even a low dose of plasma exposure could introduce a high number density of oxygen-functional groups and enhance the hydrophilicity and metal affinity of the pristine biochar. The plasma-treated biochar enabled a faster metal-adsorption rate and a 40% higher maximum adsorption capacity of heavy metal ion Pb2+. Moreover, to add more functionality to biochar surface, biochar with and without plasma pre-treatment was activated by KOH at a temperature of 800 °C. Using the same amount of KOH, the plasma treatment resulted in an activated carbon product with the larger BET surface area and pore volume. The performance of the treated activated carbon as a supercapacitor electrode was also substantially improved by>30%. This study may provide guidelines for enhancing the surface functionality and application performances of biochar using non-thermal-based techniques.

关键词: non-thermal plasma     surface functionalization     biochar modification     wastewater treatment     supercapacitor    

Machine perfusion versus cold storage of livers: a meta-analysis

null

《医学前沿(英文)》 2016年 第10卷 第4期   页码 451-464 doi: 10.1007/s11684-016-0474-7

摘要:

Different organ preservation methods are key factors influencing the results of liver transplantation. In this study, the outcomes of experimental models receiving donation after cardiac death (DCD) livers preserved through machine perfusion (MP) or static cold storage (CS) were compared by conducting a meta-analysis. Standardized mean difference (SMD) and 95% confidence interval (CI) were calculated to compare pooled data from two animal species. Twenty-four studies involving MP preservation were included in the meta-analysis. Compared with CS preservation, MP can reduce the levels of aspartate aminotransferase (AST), alanine aminotransferase (ALT), lactate dehydrogenase (LDH), and hyaluronic acid (HA) and the changes in liver weight. By contrast, MP can enhance bile production and portal vein flow (PVF). Alkaline phosphatase (ALP) levels and histological changes significantly differed between the two preservation methods. In conclusion, MP of DCD livers is superior to CS in experimental animals.

关键词: machine perfusion     cold storage     DCD     meta-analysis    

Optimization of cold-end system of thermal power plants based on entropy generation minimization

《能源前沿(英文)》 2022年 第16卷 第6期   页码 956-972 doi: 10.1007/s11708-021-0785-5

摘要: Cold-end systems are heat sinks of thermal power cycles, which have an essential effect on the overall performance of thermal power plants. To enhance the efficiency of thermal power plants, multi-pressure condensers have been applied in some large-capacity thermal power plants. However, little attention has been paid to the optimization of the cold-end system with multi-pressure condensers which have multiple parameters to be identified. Therefore, the design optimization methods of cold-end systems with single- and multi-pressure condensers are developed based on the entropy generation rate, and the genetic algorithm (GA) is used to optimize multiple parameters. Multiple parameters, including heat transfer area of multi-pressure condensers, steam distribution in condensers, and cooling water mass flow rate, are optimized while considering detailed entropy generation rate of the cold-end systems. The results show that the entropy generation rate of the multi-pressure cold-end system is less than that of the single-pressure cold-end system when the total condenser area is constant. Moreover, the economic performance can be improved with the adoption of the multi-pressure cold-end system. When compared with the single-pressure cold-end system, the excess revenues gained by using dual- and quadruple-pressure cold-end systems are 575 and 580 k$/a, respectively.

关键词: cold-end system     entropy generation minimization     optimization     economic analysis     genetic algorithm (GA)    

Corrosion behavior of metallic alloys in molten chloride salts for thermal energy storage in concentrated

Wenjin Ding, Alexander Bonk, Thomas Bauer

《化学科学与工程前沿(英文)》 2018年 第12卷 第3期   页码 564-576 doi: 10.1007/s11705-018-1720-0

摘要:

Recently, more and more attention is paid on applications of molten chlorides in concentrated solar power (CSP) plants as high-temperature thermal energy storage (TES) and heat transfer fluid (HTF) materials due to their high thermal stability limits and low prices, compared to the commercial TES/HTF materials in CSP-nitrate salt mixtures. A higher TES/HTF operating temperature leads to higher efficiency of thermal to electrical energy conversion of the power block in CSP, however causes additional challenges, particularly increased corrosiveness of metallic alloys used as containers and structural materials. Thus, it is essential to study corrosion behaviors and mechanisms of metallic alloys in molten chlorides at operating temperatures (500–800 °C) for realizing the commercial application of molten chlorides in CSP. The results of studies on hot corrosion of metallic alloys in molten chlorides are reviewed to understand their corrosion behaviors and mechanisms under various conditions (e.g., temperature, atmosphere). Emphasis has also been given on salt purification to reduce corrosive impurities in molten chlorides and development of electrochemical techniques to in-situ monitor corrosive impurities in molten chlorides, in order to efficiently control corrosion rates of metallic alloys in molten chlorides to meet the requirements of industrial applications.

关键词: corrosion mechanisms     impurities     metallic corrosion     salt purification     electrochemical techniques    

Survey of thermal comfort in residential buildings under natural conditions in hot humid and cold wet

Changhai PENG

《结构与土木工程前沿(英文)》 2010年 第4卷 第4期   页码 503-511 doi: 10.1007/s11709-010-0095-1

摘要: Comfort standards (ISO 7730, ASHRAE 55) specify the exact physical criteria for producing acceptable thermal environments, such as temperature, air movement, and humidity limits. These, however, are often difficult to comply with, particularly in hot humid and cold wet seasons in Nanjing, China. Changing expectations of comfort is important in evaluating comfort, since naturally conditioned buildings in Nanjing are not typically air-conditioned. For this objective, a field study was conducted during the summer of 2000 and the winter of 2001. A total of 600 participants each answered a subjective questionnaire. Analyzing these field data shows that in natural conditions, the influence of gender and age on people’s thermal sensations is insignificant compared with six main variables. In addition, people’s thermal discomfort rapidly increases along with growth in relative humidity. Further, the variation of people’s hot or cold sensations is in proportion to that of air movement, and the effect in winter is greater than that in summer. The range of acceptable temperatures in hot humid and cold wet Nanjing is between 14.14°C and 29.42°C.

关键词: thermal comfort     naturally conditioned     hot humid     cold wet     Nanjing    

Performance improvement of a pulse tube cryocooler with a single compressor through cascade utilization of coldenergy

Xuming LIU, Xiafan XU, Biao YANG, Xiaotong XI, Liubiao CHEN, Junjie WANG, Yuan ZHOU

《能源前沿(英文)》 2021年 第15卷 第2期   页码 345-357 doi: 10.1007/s11708-020-0708-x

摘要: The high-frequency pulse tube cryocooler (HPTC) has been attracting increasing and widespread attention in the field of cryogenic technology because of its compact structure, low vibration, and reliable operation. The gas-coupled HPTC, driven by a single compressor, is currently the simplest and most compact structure. For HPTCs operating below 20 K, in order to obtain the mW cooling capacity, hundreds or even thousands of watts of electrical power are consumed, where radiation heat leakage accounts for a large proportion of their cooling capacity. In this paper, based on SAGE10, a HPTC heat radiation calculation model was first established to study the effects of radiation heat leakage on apparent performance parameters (such as temperature and cooling capacity), and internal parameters (such as enthalpy flow and gas distribution) of the gas-coupled HPTC. An active thermal insulation method of cascade utilization of the cold energy of the system was proposed for the gas-coupled HPTC. Numerical simulations indicate that the reduction of external radiation heat leakage cannot only directly increase the net cooling power, but also decrease the internal gross losses and increase the mass and acoustic power in the lower-temperature section, which further enhances the refrigeration performance. The numerical calculation results were verified by experiments, and the test results showed that the no-load temperature of the developed cryocooler prototype decreased from 15.1 K to 6.4 K, and the relative Carnot efficiency at 15.5 K increased from 0.029% to 0.996% when substituting the proposed active method for the traditional passive method with multi-layer thermal insulation materials.

关键词: radiation heat leakage     active thermal insulation     cascade utilization     cold energy     performance improvement     cryocooler    

Optimisation for interconnected energy hub system with combined ground source heat pump and boreholethermal storage

Da HUO, Wei WEI, Simon Le BLOND

《能源前沿(英文)》 2018年 第12卷 第4期   页码 529-539 doi: 10.1007/s11708-018-0580-0

摘要: Ground source heat pumps (GSHP) give zero-carbon emission heating at a residential level. However, as the heat is discharged, the temperature of the ground drops, leading to a poorer efficiency. Borehole inter-seasonal thermal storage coupled with GSHP maintains the efficiency at a high level. To adequately utilize the high performance of combined GSHP and the borehole system to further increase system efficiency and reduce cost, such a combined heating system is incorporated into the interconnected multi-carrier system to support the heat load of a community. The borehole finite element (FE) model and an equivalent borehole transfer function are proposed and respectively applied to the optimisation to analyze the variation of GSHP performance over the entire optimisation time horizon of 24 h. The results validate the borehole transfer function, and the optimisation computation time is reduced by 17 times compared with the optimisation using the FE model.

关键词: borehole thermal storage     energy hub     ground source heat pumps (GSHP)     particle swarm optimisation    

Thermal performance of phase change material energy storage floor for active solar water-heating system

Ruolang ZENG, Xin WANG, Wei XIAO, Yinping ZHANG, Qunli ZHANG, Hongfa DI,

《能源前沿(英文)》 2010年 第4卷 第2期   页码 185-191 doi: 10.1007/s11708-009-0079-9

摘要: The conventional active solar water-heating floor system contains a big water tank to store energy in the day time for heating at night, which takes much building space and is very heavy. In order to reduce the water tank volume or even cancel the tank, a novel structure of an integrated water pipe floor heating system using shape-stabilized phase change materials (SSPCM) for thermal energy storage was developed and experimentally studied in this paper. The thermal performances of the floors with and without the SSPCM were compared under the intermittent heating condition. The results show that the Energy Storage Ratio (ESR) of the SSPCM floor is much higher than that of the non-SSPCM floor; the SSPCM floor heating system can provide stable heat flux and prevent a large attenuation of the floor surface temperature. Also, the SSPCM floor heating system dampens the indoor temperature swing by about 50% and increases the minimum indoor air temperature by 2°C–3°C under experimental conditions. The SSPCM floor heating system has a potential of making use of the daytime solar energy for heating at night efficiently.

关键词: phase change material     energy storage ratio     active solar water-heating    

review on technologies with electricity generation potentials using liquified natural gas regasification coldenergy

《能源前沿(英文)》 2023年 第17卷 第3期   页码 332-379 doi: 10.1007/s11708-023-0863-y

摘要: In modern times, worldwide requirements to curb greenhouse gas emissions, and increment in energy demand due to the progress of humanity, have become a serious concern. In such scenarios, the effective and efficient utilization of the liquified natural gas (LNG) regasification cold energy (RCE), in the economically and environmentally viable methods, could present a great opportunity in tackling the core issues related to global warming across the world. In this paper, the technologies that are widely used to harness the LNG RCE for electrical power have been reviewed. The systems incorporating, the Rankine cycles, Stirling engines, Kalina cycles, Brayton cycles, Allam cycles, and fuel cells have been considered. Additionally, the economic and environmental studies apart from the thermal studies have also been reviewed. Moreover, the discussion regarding the systems with respect to the regassification pressure of the LNG has also been provided. The aim of this paper is to provide guidelines for the prospective researchers and policy makers in their decision making.

关键词: liquified natural gas     cold energy     power generation    

标题 作者 时间 类型 操作

A fully solid-state cold thermal energy storage device for car seats using shape-memory alloys

期刊论文

Fabrication of form stable NaCl-Al2O3 composite for thermal energy storage by cold sintering process

Bilyaminu Suleiman, Qinghua Yu, Yulong Ding, Yongliang Li

期刊论文

Numerical simulation of underground seasonal cold energy storage for a 10 MW solar thermal power plant

Zulkarnain ABBAS, Yong LI, Ruzhu WANG

期刊论文

Combined heat and power plant integrated with mobilized thermal energy storage (M-TES) system

Weilong WANG, Yukun HU, Jinyue YAN, Jenny NYSTR?M, Erik DAHLQUIST

期刊论文

Experimental study and assessment of thermal energy storage mortar with paraffin/recycled brick powder

Luchen HAO; Jianzhuang XIAO; Wanzhi CAO; Jingting SUN

期刊论文

Encapsulation of polyethylene glycol in cellulose-based porous capsules for latent heat storage and light-to-thermal

期刊论文

Non-thermal plasma enhances performances of biochar in wastewater treatment and energy storage applications

期刊论文

Machine perfusion versus cold storage of livers: a meta-analysis

null

期刊论文

Optimization of cold-end system of thermal power plants based on entropy generation minimization

期刊论文

Corrosion behavior of metallic alloys in molten chloride salts for thermal energy storage in concentrated

Wenjin Ding, Alexander Bonk, Thomas Bauer

期刊论文

Survey of thermal comfort in residential buildings under natural conditions in hot humid and cold wet

Changhai PENG

期刊论文

Performance improvement of a pulse tube cryocooler with a single compressor through cascade utilization of coldenergy

Xuming LIU, Xiafan XU, Biao YANG, Xiaotong XI, Liubiao CHEN, Junjie WANG, Yuan ZHOU

期刊论文

Optimisation for interconnected energy hub system with combined ground source heat pump and boreholethermal storage

Da HUO, Wei WEI, Simon Le BLOND

期刊论文

Thermal performance of phase change material energy storage floor for active solar water-heating system

Ruolang ZENG, Xin WANG, Wei XIAO, Yinping ZHANG, Qunli ZHANG, Hongfa DI,

期刊论文

review on technologies with electricity generation potentials using liquified natural gas regasification coldenergy

期刊论文